YetiDave wrote:. Afaik it's the nitric oxide which acts as the anti microbial. I just don't know how quickly that breakdown occurs from nitrite to its oxide
I don't think the precise mechanism of how the Nitrite inhibits bacterial growth is fully understood but it is known to inhibit specific areas of bacterial metabolism. It also has different potency on different types of bacteria. Its effectiveness is shown to increase at lower pH (more acid) and so it is probably in the form of nitrous acid that it has more effect, rather than after it has broken down to nitric oxide. You may be right, but I cannot find any published documentation to support this.